“Electrochemistry of Some Metal-Metal Bonded Transition Metal Cluster Complexes in a Room-Temperature Chloroaluminate Molten Salt”
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چکیده
منابع مشابه
Pi-bonded quinonoid transition-metal complexes.
Coordination of the carbocyclic ring of hydroquinones to electrophilic transition-metal fragments such as Mn(CO)3+ and Rh(COD)+ produces stable pi-bonded eta6-complexes that are activated to facile reversible deprotonation of the -OH groups. The deprotonations are accompanied by electron transfer to the transition metal, which acts as an internal oxidizing agent or electron sink. With manganese...
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ژورنال
عنوان ژورنال: ECS Proceedings Volumes
سال: 1990
ISSN: 0161-6374,2576-1579
DOI: 10.1149/199017.0367pv